高级检索

西溪湿地臭氧变化特征及其影响因素分析

Ozone variation characteristics and influencing factors in the Xixi Wetland

  • 摘要: 西溪湿地作为中国独特的城市湿地,植被茂盛、水系发达,具有重要的生态价值和文化价值。据监测,2023年西溪湿地小时臭氧(O3)浓度超标天数达40 d以上,溯源污染源以助力精准治污迫在眉睫。考虑到湿地内部低频的人类活动和丰富的植物多样性,植物源挥发性有机物(BVOCs)可能是造成湿地臭氧超标的关键因素,因此,本研究收集了2023年11月至2024年11月西溪湿地每小时气象数据(气温、气压、空气湿度、风速、降水量),空气质量数据(PM2.5、PM10、SO2、NO2、CO、O3),以及重要环境因素(土壤温度、湿度、商户油烟值和交通流量),采用趋势分析、随机森林模型和非负矩阵分解(NMF)源解析,对湿地O3浓度变化特征及其影响因素进行了定量分析。研究结果表明,湿地臭氧浓度在日间和季节间变化趋势明显,白天和夏季相对较高;随机森林模型输出的特征重要性排序结果表明,土壤−大气湿度差和NO2对O3影响最为显著,贡献率分别为44.6%和19.0%;NMF模型归因了3类潜在污染源,分别为交通源、生活和餐饮源、自然或区域源,贡献率分别为18.7%、24.0%、57.3%;西溪湿地内的餐饮油烟和汽车尾气排放相对有限,O3超标更有可能是植物在夏季大量释放BVOCs所致。建议西溪湿地臭氧超标的主要治理方向集中在控制区域源的BVOCs、NO2和非甲烷总烃的排放上,做好湿地植物配置、鼓励绿色出行、加强监管疏导等科学管控。

     

    Abstract: As a unique urban wetland in China, the Xixi Wetland is characterized by lush vegetation, an intricate water system, and holding significant ecological and cultural value. Monitoring data revealed that the hourly ozone (O3) concentration in the Xixi Wetland exceeded standards on more than 40 days in 2023, highlighting the urgent need for precise pollution source tracing. Considering the low-frequency human activities and rich plant diversity within the wetland, biogenic volatile organic compounds (BVOCs) from plants may be a key factor contributing to the high ozone levels. Therefore, this study collected hourly meteorological data (temperature, atmospheric pressure, humidity, wind speed, rainfall), air quality data (PM2.5, PM10, NO2, SO2, CO, O3), as well as important environmental factors (soil moisture and temperature, merchant grease emissions, and traffic volume) from November 2023 to November 2024. A quantitative analysis of the characteristics of O3 concentration changes and their influencing factors was conducted using trend analysis, random forest modeling, and non-negative matrix factorization (NMF). The research results showed that: ozone concentrations in the wetland exhibited significant daily and seasonal variation, with higher levels during the day and in summer. The feature importance ranking from the random forest model indicated that the soil-atmosphere humidity difference and NO2 had the most significant impacts on O3, accounting for 44.6% and 19.0%, respectively. The NMF model identified three potential pollution source categories inlcuding traffic sources, residential and catering sources, and natural or regional sources with respective contribution rates of 18.7%, 24.0%, and 57.3%. Emissions from catering grease and vehicle exhaust within the Xixi Wetland were relatively limited, suggesting that the exceedance of O3 concentration was more likely due to the substantial release of BVOCs from plants in summer. Therefore, it is recommended that future management of ozone exceedance in the Xixi Wetland focuses on controlling emissions of BVOCs, NO2, and total non-methane hydrocarbons from regional sources, optimizing plant configurations in the wetland, encouraging green transportation, and enhancing supervision and guidance.

     

/

返回文章
返回